GAS KINETICS AN INTRODUCTION TO THE KINETICS OF HOMOGENEOUS GAS REACTIONSPDF电子书下载

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1．INTRODUCTION 1

1．1 General Survey 1

1．2 The Notation of Chemical Kinetics 3

1．3 Chemical Kinetics and Thermodynamics 8

2．THE THEORIES OF CHEMICAL KINETICS AND ENERGY TRANSFER 22

2．1 The Collision Theory of Bimolecular Reactions 23

2．2 The Transition State Theory of Chemical Kinetics 25

2．3 The Theory of Unimolecular Reactions 45

2．4 Energy Transfer in Unimolecular Reactions 53

2．5 Experimental Work on Energy Transfer in Chemical Reactions 64

2．6 The Transfer of Energy between Molecules 82

3．UNIMOLECULAR DECOMPOSITIONS AND BIMOLECULAR COMBINATIONS 97

3．1 Radical Elimination Reactions and the Combination of Radicals 98

3．2 Molecular Elimination and Molecular Association Reactions 126

3．3 Isomerizations and Racemizations 137

3．4 Thermal Decompositions involving Chain Mechanisms 142

3．5 Thermal Decompositions in the presence of Nitric Oxide 153

3．6 Relations between Activation Energies and A Factors 160

4．TRANSFER REACTIONS 168

4．1 The Metathetical Reactions of Atoms resulting in the Transfer of a Hydrogen Atom 168

4．2 The Metathetical Reactions of Free Radicals 195

4．3 Metathetical Reactions not involving the Transfer of Hydrogen Atoms 212

4．4 The General Properties of Metathetical Reactions 223

4．5 The Disproportionation of Free Radicals 232

4．6 Inversion Reactions 237

4．7 The Reactions of Excited Atoms,Radicals and Molecules 242

4．8 Four-Centre Reactions 255

4．9 Termolecular Reactions 262

5．RADICAL DECOMPOSITIONS AND RADICAL ADDITIONS 281

5．1 The Addition of Atoms to Carbon-Carbon Double Bonds 283

5．2 The Addition of Radicals to Carbon-Carbon Double Bonds 294

5．3 The Addition of Atoms and Radicals to Compounds which do not contain Carbon-Carbon Double Bonds 297

5．4 The Unimolecular Decompositions of Free Radicals 299

SUBJECT INDEX 311

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